Using DNA To Convert Carbon Dioxide Into Valuable Products

By taking inspiration from biological porphyrins and combining it with the specificity of DNA hybridization, a group of researchers from MIT have developed an improved electrocatalyst platform for CO2 reduction. The addition of single-stranded DNA to the porphyrin-based catalysts improved their stability, and DNA-catalyst conjugates were immobilized on screen-printed carbon electrodes using DNA hybridization with nearly 100% efficiency. Increased turnover frequency (TOF) and catalyst stability were observed with the DNA-immobilized catalysts as compared to the unmodified small molecules. This work demonstrates the importance of taking inspiration from Nature and demonstrates the potential of DNA hybridization as a general strategy for molecular catalyst immobilization.



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